Is this really a .NET question? Or is it an HTML question?
You can create a CSS class for positioning your label if you'd like, then just set the labels CssClass property. Maybe use the css property float:left for the label?
So your css will look something like:
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<style type="text/css">
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.labelStyle
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{
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float:left;
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}
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</style>
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Your HTML will look something like:
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<table>
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<tr><td>...</td></tr>
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</table>
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<asp:label id="Lbl_mylabel" runat="server" CssClass="labelStyle"></asp:label>
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By setting an element's float, you indicate to the browser that the rest of the website's content should be displayed on one side of that element. In this case your table will be displayed on the Left Of Your Label.
Cheers,
-Frinny