This the method is, I must admit, a bit cheeky. But it works, so who cares? ;-)
First of all, open notepad. You'll have an empty file. Save this empty file as nothing.exe, choosing All Files (*.*) under the Save as type: option. Choose any place you'll remember and that you have writing access to, it doesn't matter as we'll delete it later anyway.
Next, we'll need to change the settings for this file type. There are two ways to do that. Either:
Find a xyz-file somewhereor:
-> do a right click on it
-> choose Properties
-> click on the Change button behind Opens with:
Go to the Start-menuIn either case, you'll have the option to change the program to open this file type with. So, click on Browse, select the nothing.exe file you created earlier, click Open and then OK. Now delete the nothing.exe file. You're done.
-> click Default Programs
-> choose Associate a file type or protocol with a program
-> find and left click on the extension / association you're trying to delete
-> click Change program
Now, for those who were thinking of the commands assoc and ftype - they don't do the job. Vista (and maybe previous versions of Windows too, I don't know) seems to have separate ways of registering the associations registered with them and via the GUI. If anyone can enlighten me on this issue, they are welcome to do so.