As msquared says you have to try something first and then we can help. The best way to learn is to try it yourself first even if you make mistakes.
Try reading this article by msquared to get you started.
http://www.thescripts.com/forum/thread585228.html
Before starting your design you MUST first determine your business rules. Business rules will determine your tables, relationships and in limited cases some fields. Business rules are things you want your database to track and the rules that apply to the database.
For instance in your case what do you need to track for a filling station? Ask yourself that and it will get you started. ie: Do you need to track customers, do you need to track type of fuel sold, do you need to track amount of fuel sol for each type, etc. etc. That is if a filling company is a gas station (lol).